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The use of magnesium, the lightest metallic construction material, is on the rise – above all in the automotive industry. To lower the attendant risk of a magnesium fire triggered by oxygen, sulfur hexafluoride (SF6) or sulfur dioxide (SF6) have been used to date. Sulfur dioxide is toxic and therefore subject to rigorous safety precautions when used in foundries. Sulfur hexafluoride, in turn, has a high global warming potential or GWP factor of 23,900 – with respect to the damage caused to the earth’s atmosphere by CO2. The use of sulfur hexafluoride for cast magnesium has therefore been banned with effect at January 1, 2007, unless the quantity involved remains below 500 kilograms per annum.

Linde Gas has developed and filed a patent for a procedure that eliminates these problems. Using dry ice as a covering agent and protective gas, magnesium melts are effectively shielded from the ingress of oxygen.

Hanover, Germany
There is no magic formula for solving global problems. But there are innovative ideas from Linde. A magnesium liquefaction technology developed by Linde uses dry ice to protect highly sensitive magnesium from atmospheric oxygen. Sulfur hexaflouride, which has been traditionally used, has a global warming potential nearly 24,000 times higher than that of carbon dioxide. This innovation represents our contribution to making magnesium processing more environmentally compatible.

This procedure was developed as part of a research project funded by Germany’s Ministry for Education and Research (BMBF) together with a number of other partners.

At this year’s “TMS 2005” conference, the world’s largest international congress on new developments in the field of materials engineering, a Linde Gas application was one of the eleven entries to win an environment prize – from a total of 2,300 submissions.


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